Differentiation Among Romanian Wine Regions Based on Lead Isotope Signatures

Florin Dumitru BORA, Anamaria CĂLUGĂR, Claudiu Ioan BUNEA, Ionut RACZ


The objective of this study is to determine the Pb concentration and 206Pb/204Pb, 206Pb/207Pb, 206Pb/208Pb from several Romanian winemaking regions, in order to highlight credible geographical markers of wine origin. The Pb level concentration and the ratios of 206Pb/204Pb, 206Pb/207Pb, 206Pb/208Pb were determined in 25 white and 9 red wines using ICP-MS techniques. Based on 206Pb/207Pb isotope ratios it can be concluded that the vines grown in the Tîrnave vineyard [Blaj (1.1790 average value)], Huși vineyard [Huși (1.1958 average value wine center), Averești (1.1908 average value)] and Iași vineyard [Copou (1.1875 average value) wine center], show traces of atmospheric pollution with lead [if 206Pb/207Pb=~1.1700-1.2200 (atmospheric pollution)]. Combining the 206Pb/204Pb with 206Pb/208Pb isotopic ratio may carry out a separation on the vineyards and wine-growing centers. Based on 206Pb/204Pb, 206Pb/207Pb and 208Pb/206Pb a separation of the wine samples was possible.


geographic origin; isotope ratio; wine fingerprint.

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DOI: http://dx.doi.org/10.15835/buasvmcn-hort:2019.0007

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